From oil spill to toxic waste: The polymer solution

In the aftermath, authorities followed standard practice, neutralizing the red mud with acetic acid. Gerard Caneba, a professor of chemical engineering at Michigan Technological University, believes an unlikely chemical may work even better--and might transform toxic sludge into a valuable raw material.

Vinyl acetate polymers that are being developed in Caneba's lab have a near-neutral pH when they are dissolved in water, but something intriguing happens if you mix the solution in an alkaline substance like red mud, which has pH levels as high as 13. "When you put it in a base environment, poly(vinyl acetate) converts to poly(vinyl alcohol), and it also kicks out acetic acid within a minute," he said.

Thus, while it is neutralizing the red mud, the poly(vinyl acetate) is also creating a valuable product. A resulting solid material has potential uses in landscaping, insulation and construction. "We did tests and got really nice performance values on simulated alumina tailings," Caneba said. And there's no shortage of potential sites: "They have about 20 alumina repositories in Hungary and could use this method to clean up any contaminated places. Other sources are found in Texas and Louisiana and wherever aluminum is being manufactured from bauxite ore."

This puts a smile on his face. "I like this mechanism," he says. "We're not just cleaning the stuff up with acetic acid. We can neutralize toxic waste and turn it into something benign and useful."

Caneba has been working with the Hungarian Academy of Sciences to further test the process. Promising preliminary results are included in his new book, which details his research on vinyl acetate polymer solutions. He is also working with mining giant Rio Tinto, which is providing him with actual red mud samples.

Caneba is also developing next-generation chemicals from vinyl acetate polymers that could be used to clean up oil spills and disperse spilled oil. With researchers from Gulf Coast universities, he has been working to obtain funds to investigate this family of polymer surfactants.

In particular, the new surfactants could address deep oil plumes like those from last summer's disastrous spill in the Gulf of Mexico. Deep underwater, these eruptions of hot petroleum exploding from beneath the earth are quickly compressed and chilled in the ocean depths. "It's no surprise that you can have lingering plumes, and that they are particularly difficult to break up," said Caneba. "We think our formula will be able to help break down the oil better, so microbes can eat it up.

reystenveden: Acetic Acid Formula

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Acetic Acid Formula - Bookshelf

Acetic acid and its derivatives

Acetic acid and its derivatives

;The book provides comprehensive physical property data for compounds and their separation, including acetic acid-water separation.

Elements of chemistry, for the use of colleges, academies, and schools

Elements of chemistry, for the use of colleges, academies, and schools

The acetic acid might be tribasic, and the formula of acetate of silver 3AgO, ClsH000, that of the concentrated acetic ...

The Quarterly journal of the Chemical Society of London

The Quarterly journal of the Chemical Society of London

The low price at which pure acetic acid may be obtained by the method above described, will probably lead to a more extended use of it in dyeing and calico ...

Practical mataria medica and prescription writing

Practical mataria medica and prescription writing

Eng., Acetic Acid. Formula, HC2H^O2. A colorless liquid containing not less than 36 per cent, by weight of absolute Acetic Acid. Acidum Aceticum Dilutum. ...

Beilstein handbook of organic chemistry, fourth edition, fifth supplementary series, covering the literature from 1960 through 1979

Beilstein handbook of organic chemistry, fourth edition, fifth supplementary series, covering the literature from 1960 through 1979

Indol-3-yl-acetic acid pentachlorophenyl ester C16H8C15NO2, formula I (R = C6C15 ). Prep. From indol-3-yl-acetic acid and pentachlorophenol [DCC] (JC Hart et ...

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Acetic acid - Wikipedia, the free encyclopedia
Acetic acid is an organic compound with the chemical formula CH3COOH. ... In households, diluted acetic acid is often used in descaling agents. ...

Acetic acid
Acetic acid is one of the simplest carboxylic acids (the second-simplest, next to formic acid) ... Acetic acid has the empirical formula CH2O and the molecular formula C2H4O2 or ...

Acetic acid
Acetic acid is one of the simplest carboxylic acids (the second-simplest, next to formic acid) ... Acetic acid has the empirical formula CH2O and the molecular formula C2H4O2. ...

What is the chemical formula of acetic acid? - Yahoo! Answers ...
18 Yahoo! Answers - What is the chemical formula of acetic acid? – Discover the answer for this question and Earn more points for the best answer on Yahoo! Answers India

Acetic acid - New World Encyclopedia
Acetic acid has the empirical formula CH2O and the molecular formula C2H4O2. ... Acetic acid-producing bacteria are present throughout the world, and any culture ...